How much longer can we use fertilizers?
Phosphorus, Phosphates
Phosphorus, chemical symbol P, is one of several nutrients that are important in the production of food. It has atomic number 15. It is very reactive, so it never occurs as an element in nature; only as compounds. There are several naturally-occurring compounds that contain phosphorus. They have low solubility and volatility, so there is little naturally-occurring phosphorus dissolved in lakes, rivers and seas, and virtually none in the atmosphere. Most phosphorus is found in the Earth's crust. Phosphorus found in the soil tends to be bound up in particles and not available to plants. Water in soil can contain dissolved ions of phosphorus that plants can take up. It generally occurs as the negatively charged phosphate ion PO43-; otherwise it forms insoluble chemical compounds with other elements that become part of the soil. Clay soil particles are negatively charged, so they repel phosphates which are easily leached out of the soil. These particles are carried along in rivers and end up as sediments at the bottom of lakes, so it is important to try and minimize erosion. Sediments with high concentrations of phosphorus can contribute to eutrophication, which can lead to algal blooms and fish deaths. Phosphorus is a starting material for photosynthesis.
Farmers often add phosphorus to fields in NPK fertilizers (N = nitrogen and K = potassium), and the absence of each nutrient can affect the take up of the others. Phosphorus compounds are also present in domestic sewage and some industrial waste. Detergents also used to be a major source (in the form of sodium tripolyphosphate (STPP)), but since the early 1980's have been replaced by non-phosphorous versions in many countries. Phosphorus compounds are not removed by normal sewage treatment.
Tropical rain forests appear very lush, and when they are burnt, phosphorus and potassium from the upper soil are released, which helps the first year's crops to be bountiful. The high levels of rainfall leach out the nutrients quickly, however.
Apart from the problems caused by the use of fertilizers, a lot of energy is needed to mine the raw materials, which usually entails fossil fuels. They are only mined in relatively few areas, including Canada, China, Morocco, the UK and the former USSR. In the United states there are deposits in Florida, Idaho, Tennessee, and Utah but these are likely to be depleted in 2035. Another risk is in the manufacture of phosphates: water is used in the processing of phosphate into the phosphoric acid that is used to make fertilizer. The ponds that hold the acidic water can be breached, particularly during hurricanes in the USA.
Phosphorus is found in the DNA and RNA of all living cells, and is essential for life. Adenosine triphosphate (ATP) is used to transport energy.
As well as being used for fertilizers and detergents, phosphorus is used for fireworks, explosives, friction matches, bombs, baking powder, methamphetamine and toothpaste. Calcium phosphate is used to make fine china.
Organic compounds containing phosphorus are called organophosphates, and they are used as part of insecticides (including sheep dips), herbicides, and nerve gases, etc. They are used against West Nile Virus, for example. They can damage people (for example farm workers) who are regularly exposed to them, and children.
Judge to Determine Next Step in Everglades
Phosphorus fertilizer runoff has polluted the Everglades, upsetting the balance of plants that grow there. An $8.4 billion court-ordered clean-up began a decade ago. Environmentalists and the local Miccosukee Tribe of Indians say that the government cannot meet its Dec. 31, 2006 targets, and a Miami U.S. District Judge has ordered hearings starting Monday.
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